Şeref Ertul,1,* Hacı Ahmet Tombak,1,2 Mevlüt Bayrakcı1 and Orhan Merter1
1 Department of Chemistry, Selc¸uk University, 42031, Konya, Turkey
2 Department of Nuclear Medicine, Selc¸uk University, 42031, Konya, Turkey
* Corresponding author: E-mail: sertul42@gmail.com,
mevlutbayrakci@gmail.com
Abstract
The article describes the syntheses and extraction properties of new lactam
ionophores. These lactam derivatives were
easily synthesized via aminolysis of 2,2’-methylenebis(4-chlorophenol)
dimethylester or its corresponding acyl chloride
with corresponding diamine compounds in THF or methanol-dichloromethane solvent
systems in one step, respectively.
The extraction studies of lactam ionophores were performed toward dichromate
anion and alkaline and transition
metal cations such as Li+, Na+, K+, Co2+, Hg2+ and Pb2+. All the structures of
the ionophores were confirmed by spectroscopic
techniques and elemental analysis.
Keywords: Lactam, chromate extraction, picrate extraction, liquid-liquid extraction