SELECTIVE DEALKYLATION OF TETRA-O-PROPYL-p-tert-BUTYL CALIX[4]ARENE AT THE LOWER RIM BY AlCl3

Saeed Taghvaei-Ganjali, Atoussa Modjallal
Department of Environmental Engineering, Faculty of Environment, University of Tehran, Tehran, Iran,
Fax:+98-21-658111,  e-mail: taqvaee@khayam.ut.ac.ir
 

Abstract
As a result of experimental studies on the dealkylation of tetra-O-propyl-p-tert-butyl calix[4]arene 1, we have found that by treating 1 with the stoichiometric amount of AlCl3, the tri, di and mono-O-propyl-p-tert-butyl calix[4]arene are obtained in good yield. In these reactions tert-butyl groups at the upper rim are uchanged.