Inorganic Crystal Structure Prediction – a Dream Coming True?
Anton Meden
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, SI-1000 Ljubljana
Absrtract
Various approaches to gain understanding of crystal building
principles are classified in two groups. The first being crystal-chemical
analysis of known structures and deriving crystallographic rules thereof, while
the second is a quantum-chemical stability calculation, combined with local or
global energy minimization. Both approaches are discussed in terms of their
applicability to crystal structure prediction of inorganic solids. The meaning
of a successful structure prediction is defined and its applicability outlined.
Anticipation of further development is given at the end.
Key words: Inorganic crystal structure prediction, data mining, quantum chemical calculations.