Zita Valentová,a Emanuel Makrlík,b,*
a
V. Nezvala 758, 272 04 Kladno, Czech Republic
b Faculty of Applied Sciences, University of West Bohemia, Husova 11,
306 14 Pilsen,Czech Republic.
E-mail: petr.vanura@vscht.cz.
Abstract
The extraction of
microamounts of strontium by a nitrobenzene solution of hydrogen
dicarbollylcobaltate (H+B–) in the presence of Slovafol
909 (p-nonylphenylnonaethylene
glycol, L) as a synergic agent has been investigated. The equilibrium data have
been explained assuming that the complexes HL+, HL2+,
SrL2+ and SrL2 2+ are extracted into the
organic phase. The values of extraction and stability constants of the species
in nitrobenzene saturated with water have been determined.
Keywords: Strontium, nitrobenzene, hydrogen dicarbollylcobaltate, p-nonylphenylnonaethylene glycol, extraction and stability constants