Internal Pressure, Energy of Vaporization and Solubility Parameter of Pb–Sn Molten Binary Mixture at Elevated Temperatures

Rajeev Kumar Shukla,^1,* Atul Kumar,¹ Neetu Singh² and Umakanti Tiwari²

¹Department of Chemistry, V.S.S.D. College, Nawabganj, Kanpur(India) 208002
²Department of Chemistry, A.N.D. College, Kanpur(India)
* Corresponding author: E-mail: rajeevskukla47@rediffmail.com

Abstract
Internal pressure, excess internal pressure, energy of vaporization, excess energy of vaporization and solubility parameter of Pb–Sn molten binary liquid mixture were calculated over a wide range of temperature and composition. A quantitative treatment has been carried out for these thermodynamic properties with the help of Hildebrand equation. Also, interaction study has been made in the light of excess thermodynamic functions.

Keywords: Molten, internal pressure, elevated temperature, binary mixture, solubility parameter, hildebrand equation.