Ahmet Orhan Görgülü,a,* Hüseyin Çelikkanb and Mustafa Arslana
a Chemistry Department, Firat University, TR-23169, Elazig, Turkey
b Chemistry Department, Gazi University, TR-06500, Ankara Turkey
* Corresponding author: E-mail: aogorgulu@firat.edu.tr;
fax: +90-424-2330062
Abstract
1,3-di(2-methylpiperidino)propan-2-ol (ROH) was synthesized 1,3-
dichloropropan-2-ol with 2-methlypiperidine.
Potassium 1,3-di(2-methylpiperidino)propan-2-O-xanthate (ROCSSK) was obtained
from the reaction of 1,3-di(2-
methylpiperidino)propan-2-ol (ROH) with carbon disulfide and metallic potassium.
All products were generally obtained
in high yields. xanthate complexes of Co(II), Ni(II) and Cu(I) was synthesized
in the medium water as
[CoL2(H2O)2], [NiL2(H2O)2].2H2O and [CuL].2H2O. The novel xanthate ligand and
its complexes were defined by FTIR,
1H and 13C NMR spectroscopies, elemental analyses, magnetic susceptibility and
TGA techniques. [CoL2(H2O)2]
and [NiL2(H2O)2].H2O complexes were subjected to cyclic voltammetry using Pt
working electrode and Ag/AgCl (3 M
KCl) reference electrode.
Keywords: Co(II), Ni(II) and Cu(I) complexes, xanthate, cyclic voltammetry