Surabhi Siva Kumar* and Kochu Govindan Sudarsan
Department of Chemistry, Anil Neerukonda Institute of Technology and Sciences,
Sangivalasa,
Visakhapatnam-531 162, India.
* Corresponding author: E-mail: siva_ks9123@rediffmail.com
Abstract
The applicability of uranium antimonate (USb) for the efficient removal of
strontium from aqueous acidic solutions by
adsorption has been investigated. The adsorption data analysis was carried out
using the Freundlich and Langmuir isotherms
for the uptake of Sr in the initial concentrations range 1.14 × 10–4 to 1.14 ×
10–2 mol L–1 on USb from nitric acid
medium. The adsorption process is heterogeneous in nature as evident from the
fractional value (0.48) of β. The sorption
capacity ’b’ was found to be 18.81 mg g–1 from 0.5 mol L–1 nitric acid medium.
Equilibrium adsorption values at
different temperatures have been utilized to evaluate the change in enthalpy,
entropy and free energy. The adsorption of
strontium on USb was found to be endothermic.
Keywords: Strontium, uranium antimonate, adsorption, inorganic exchanger, adsorption isotherms.